Ultra-thin NaCl films as protective layers for graphene

超薄 NaCl 薄膜作为石墨烯的保护层

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作者:Irene Palacio, Koen Lauwaet, Luis Vázquez, Francisco Javier Palomares, Héctor González-Herrero, José Ignacio Martínez, Lucía Aballe, Michael Foerster, Mar García-Hernández, JoséÁngel Martín-Gago

Abstract

The ageing of graphene is an important issue that limits its technological applications. Capping layers are a good option for circumventing this problem. In this work, we propose the use of ultra-thin NaCl films as easily-removable protective layers. We have carried out a detailed characterization of the NaCl/graphene interface on metal substrates, namely Cu(111) and Ir(111), by means of complementary microscopy, electron diffraction and spectroscopic techniques. Interestingly, we show that NaCl neither interacts in a chemical way with graphene nor intercalates through it. We demonstrate that the NaCl film is stable under ambient conditions, protecting the graphene surface from oxidation. In addition, after removing the protective layer, graphene remains intact.

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