Influence of Operational Strategies for the Recovery of Magnesium Hydroxide from Brines at a Pilot Scale

中试规模下操作策略对从盐水中回收氢氧化镁的影响

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Abstract

The continuous depletion of minerals caused by land mining and the increase in their demand have pushed the development of novel sustainable technological processes for mineral recovery from unconventional sources. In this context, magnesium (Mg) has gained considerable attention for its peculiar properties and high relevance of its compounds, such as magnesium hydroxide, Mg(OH)(2). In the present work, the influence of several operating conditions on the Mg(OH)(2) precipitation process was thoroughly investigated by adopting a novel multiple feed-plug flow reactor. The influence of (i) initial Mg(2+) concentrations in the feed stream; (ii) brine and alkaline flow rates; and (iii) the product recycling strategy (seeded crystallization) was considered. The results marked the possibility of improving sedimentation and filterability properties of Mg(OH)(2) suspensions by adopting the recycling strategy to overcome industrial issues associated with the production of Mg(OH)(2) suspensions using NaOH solutions.

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