Wavelength multiplexing infrared metasurfaces for protein recognition and trace detection

用于蛋白质识别和痕量检测的波长复用红外超表面

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Abstract

Infrared metasurfaces have exhibited exceptional optical properties that differ from naturally occurring metallic and dielectric nanostructure, enabling non-destructive and label-free sensing in a broadband region. However, implementing wavelength multiplexing sensors in broadband infrared has faced significant challenges. These challenges arise from the difficulty in efficiently exciting high Q resonances at specific wavelengths and the inability to individually tune each resonance. Herein, we present a dual resonant metasurface that utilizes a metal-dielectric-metal plasmonic grating and a dielectric-metal channel. By adjusting the vertical and horizontal structures of metasurface, we can independently modify the spectrum of the metasurface in the near-infrared and mid-infrared regions. This broadband infrared metasurface exhibits robust spectral regulation, enabling a polarization-dependent strategy for the dual-resonance. It offers a competitive advantage over traditional metallic nanostructure in refractive index sensing at the second near-infrared window and ultrasensitive vibrational spectroscopy in mid-infrared. Specifically, our proposed metasurface achieves protein concentration sensing and dynamic monitoring of protein concentration in the infrared two-zone. Additionally, it enhances the mid-infrared absorption of amide II with a high Q resonance. The metasurface which combines wavelength multiplexing and polarization dependent switch for protein recognition and trace detection, presents a novel approach for developing high-performance sensors and Integrated photonics sensors in the broadband infrared region.

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