Visible light mediated intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes

可见光介导的环丙基苯胺与炔烃的分子间[3+2]环加成反应

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Abstract

Intermolecular [3 + 2] annulation of cyclopropylanilines with alkynes is realized using visible light photoredox catalysis, yielding a variety of cyclic allylic amines in fair to good yields. This method exhibits significant group tolerance particularly with heterocycles. It can also be used to prepare complex heterocycles such as fused indolines.

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