Abstract
Lithium niobate (LiNbO(3)) crystals are important dielectric and ferroelectric materials, which are widely used in acoustics, optic, and optoelectrical devices. The physical and chemical properties of LiNbO(3) are dependent on microstructures, defects, compositions, and dimensions. In this review, we first discussed the crystal and defect structures of LiNbO(3), then the crystallization of LiNbO(3) single crystal, and the measuring methods of Li content were introduced to reveal reason of growing congruent LiNbO(3) and variable Li/Nb ratios. Afterwards, this review provides a summary about traditional and non-traditional applications of LiNbO(3) crystals. The development of rare earth doped LiNbO(3) used in illumination, and fluorescence temperature sensing was reviewed. In addition to radio-frequency applications, surface acoustic wave devices applied in high temperature sensor and solid-state physics were discussed. Thanks to its properties of spontaneous ferroelectric polarization, and high chemical stability, LiNbO(3) crystals showed enhanced performances in photoelectric detection, electrocatalysis, and battery. Furthermore, domain engineering, memristors, sensors, and harvesters with the use of LiNbO(3) crystals were formulated. The review is concluded with an outlook of challenges and potential payoff for finding novel LiNbO(3) applications.