Abstract
Disubstituted odd-carbon cumulenes are linear carbon wires with near-degenerate helical π-orbitals. Such cumulenes are chiral molecules but their electronic structure consists of helical orbitals of both chiralities. For these helical molecular orbitals to give rise to experimentally observable effects, the near-degenerate orbitals of opposite helicities must be split. Here we show how pyramidalized single-faced π-donors, such as the amine substituent, provide a strategy for splitting the helical molecular orbitals. The chirality induced by the amine substituents allow for systematic control of the helicity of the frontier orbitals. We examine how the helical orbitals in odd-carbon cumulenes control the coherent electron transport properties, and we explicitly predict two modes in the experimental single-molecule conductance for these molecules. We also show that the current density through these linear wires exhibits strong circular currents. The direction of the circular currents is systematically controlled by the helicity of the frontier molecular orbitals, and is therefore altered by changing between the conformations of the molecule. Furthermore, the circular currents are subject to a full ring-reversal around antiresonances in the Landauer transmission, emphasizing the relation to destructive quantum interference. With circular currents present around truly linear carbon wires, cumulenes are promising candidates for novel applications in molecular electronics.