Abstract
This article presents a comprehensive analysis of the technical characteristics of advanced versatile materials used in chipless radio-frequency identification (RFID) tags and antennas. The focus is on materials that are used as radiators and substrates. Crucial aspects include flexibility, weight, size, gain, environmental sustainability, efficiency, fabrication time and type, and cost. A comprehensive set of tables are presented that summarize and compare material properties. The materials include flexible high-tech ink substances, graphene, and liquid crystals, as well as metamaterials which possess properties that allow for an increased bandwidth. Printing techniques are discussed for high-performance high-resolution fabricated tags. This paper contributes by systematically comparing emerging materials for chipless RFID tags, highlighting their impact on performance and sustainability. It also provides practical guidance for material selection and fabrication techniques to enable next-generation wireless applications. It presents a broad understanding of various materials and their use. The paper provides direction for the deployment and utilization of inexpensive passive chipless RFID tags in future intelligent wireless networks. The advancement of chipless RFID is largely driven by the development of innovative materials, especially in the realm of advanced materials and smart materials, which enable the creation of more cost-effective, flexible, and scalable RFID systems.