Abstract
P2-type layered materials (Na (x) TMO(2)) have become attractive cathode electrodes owing to their high theoretical energy density and simple preparation. However, they still face severe phase transition and low conductivity. Current research on Na (x) TMO(2) is mostly focused on the modification of bulk materials, and the application performances have been infrequently addressed. This review summarizes the information on current common P2-Na (x) TMO(2) materials and discusses their sodium-storage mechanisms. Furthermore, modification strategies to improve their performance are addressed for practical applications based on a range of key parameters (output voltage, specific capacity, and lifespan). We also discuss the future development trends and application prospects for P2 cathode materials.