Abstract
The macrocyclic supramolecular assembly confinement effect not only induces or extends the fluorescence/phosphorescence luminescence behavior of guest molecules but has also been widely applied in the research fields of chemistry, biology, and materials. This review primarily describes recent advances in cyclodextrin (CD) supramolecular assembly confined luminescent materials. Taking advantage of their hydrophobic cavity, CDs and their derivatives effectively encapsulate guest molecules and special functional groups or further assemble and polymerize to restrict the motion of guest chromophores, inducing and enhancing the luminescence behavior and realizing intelligent stimulus-responsive luminescence depending on changes in temperature, light, redox reactions and solvent polarity, which are successfully applied in targeted cell imaging, sensing, information encryption, anti-counterfeiting and flexible electronic light-emitting devices. With the emergence of new chromophores and CD primitives, spatial confinement within CD supramolecular assemblies will further realize the rapid development of supramolecular science and technology in circularly polarized luminescence, fluorescence/phosphorescence cascade energy transfer, light-harvesting energy-transfer systems and long persistent luminescent materials.