Abstract
Novel Mn-Ce-Ti-O composite aerogels with large mesopore size were prepared via a one-pot sol-gel method by using propylene oxide as a network gel inducer and ethyl acetoacetate as a complexing agent. The effect of calcination temperature (400, 500, 600, and 700 °C) on the NH(3)-selective catalytic reduction (SCR) performance of the obtained Mn-Ce-Ti-O composite aerogels was investigated. The results show that the Mn-Ce-Ti-O catalyst calcined at 600 °C exhibits the highest NH(3)-SCR activity and lowest apparent activation energy due to its most abundant Lewis acid sites and best reducibility. The NO conversion of the MCTO-600 catalyst maintains 100% at 200 °C in the presence of 100 ppm SO(2), showing the superior resistance to SO(2) poisoning as compared with the MnO(x)-CeO(2)-TiO(2) catalysts reported the literature. This should be mainly attributed to its large mesopore sizes with an average pore size of 32 nm and abundant Lewis acid sites. The former fact facilitates the decomposition of NH(4)HSO(4), and the latter fact reduces vapor pressure of NH(3). The NH(3)-SCR process on the MCTO-600 catalyst follows both the Eley-Rideal (E-R) mechanism and the Langmuir-Hinshelwood (L-H) mechanism.