Abstract
This work reports the synthesis of nanosilica-coated magnetic carbonaceous adsorbents (MCA@SiO(2)) using low-temperature hydrothermal carbonization technique (HCT) and the feasibility to utilize it for methylene blue (MB) adsorption. Initially, a carbon precursor (CP) was synthesized from corn starch under saline conditions at 453 K via HCT followed by the magnetization of CP again via HCT at 453 K. Subsequently, MCA was coated with silica nanoparticles. MCA and MCA@SiO(2) were characterized using X-ray diffraction, Fourier transform infrared, scanning electron microscopy/energy-dispersive spectroscopy, transmission electron microscopy, and Brunauer-Emmett-Teller (BET) N(2) adsorption-desorption isotherms. The BET surface area of MCA and MCA@SiO(2) were found to be 118 and 276 m(2) g(-1), respectively. Adsorption of MB onto MCA@SiO(2) was performed using batch adsorption studies and in the optimum condition, MCA@SiO(2) showed 99% adsorption efficiency with 0.5 g L(-1) of MCA@SiO(2) at pH 7. Adsorption isotherm studies predicted that MB adsorption onto MCA@SiO(2) was homogeneous monolayer adsorption, which was best described using a Langmuir model with the maximum adsorption capacity of 516.9 mg g(-1) at 25 °C. During adsorption kinetics, a rapid dye removal was observed which followed pseudo-first- as well as pseudo-second-order models, which suggested that MB dye molecules were adsorbed onto MCA@SiO(2) via both ion exchange as well as the chemisorption process. The endothermic and spontaneous nature of the adsorption of MB onto MCA@SiO(2) was established by thermodynamics studies. Mechanism of dye diffusion was collectively governed by intraparticle diffusion and film diffusion processes. Furthermore, MB was also selectively adsorbed from its mixture with an anionic dye, that is, methyl orange. Column adsorption studies showed that approximately 500 mL of MB having 50 mg L(-1) concentration can be treated with 0.5 g L(-1) of MCA@SiO(2). Furthermore, MCA@SiO(2) was repeatedly used for 20 cycles of adsorption-desorption of MB. Therefore, MCA@SiO(2) can be effectively utilized in cationic dye-contaminated wastewater remediation applications.