Synthesis of ZnMn₂O₄ Nanoparticles by a Microwave-Assisted Colloidal Method and their Evaluation as a Gas Sensor of Propane and Carbon Monoxide

微波辅助胶体法合成 ZnMn₂O₄ 纳米粒子及其作为丙烷和一氧化碳气体传感器的评价

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作者:Juan Pablo Morán-Lázaro, Erwin Said Guillen-López, Florentino López-Urias, Emilio Muñoz-Sandoval, Oscar Blanco-Alonso, Héctor Guillén-Bonilla, Alex Guillén-Bonilla, Verónica María Rodríguez-Betancourtt, Marciano Sanchez-Tizapa, María de la Luz Olvera-Amador

Abstract

Spinel-type ZnMn&sub2;O&sub4; nanoparticles were synthesized via a simple and inexpensive microwave-assisted colloidal route. Structural studies by X-ray diffraction showed that a spinel crystal phase of ZnMn&sub2;O&sub4; was obtained at a calcination temperature of 500 °C, which was confirmed by Raman and UV-vis characterizations. Spinel-type ZnMn&sub2;O&sub4; nanoparticles with a size of 41 nm were identified by transmission electron microscopy. Pellet-type sensors were fabricated using ZnMn&sub2;O&sub4; nanoparticles as sensing material. Sensing measurements were performed by exposing the sensor to different concentrations of propane or carbon monoxide at temperatures in the range from 100 to 300 °C. Measurements performed at an operating temperature of 300 °C revealed a good response to 500 ppm of propane and 300 ppm of carbon monoxide. Hence, ZnMn&sub2;O&sub4; nanoparticles possess a promising potential in the gas sensors field.

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