Fabrication and Properties of Adsorptive Ceramic Membrane Made from Kaolin with Addition of Dolomite for Removal of Metal Ions in a Multielement Aqueous System

以高岭土为原料,添加白云石制备吸附陶瓷膜,并研究其在多元素水溶液体系中去除金属离子的性能

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Abstract

The exorbitant presence of heavy metals has emerged as one of the most serious ecological issues facing the world. The treatment processes currently employed are not effective for removing all of the contaminants completely. Therefore, it is necessary for better operational technology to be developed. Here, we fabricated effective and inexpensive kaolin-based ceramic membranes with the addition of dolomite using a simple dry compaction method. Moreover, we applied the obtained adsorptive membranes to the removal of lead, copper, zinc, and cadmium from aqueous solutions. The membranes prepared with dolomite addition (sintered at different temperatures) exhibited a high water flux between 246.78 and 1738.56 L/h·m(2) at an extremely low operating pressure (0.03 MPa). Furthermore, the optimal membrane showed high removal efficiencies of 99.12, 99.82, 85.62, and 65.94% for Pb(II), Cu(II), Zn(II), and Cd(II), respectively. The utilization of dolomite enhanced the removal efficiency of the adsorptive membranes by around 32-54% in a multielement system. This work reveals that enhanced adsorptive membranes with high fluxes and strong removal abilities have great potential as a synergized system with practical applications in the removal of heavy-metal contaminants from wastewater in the future.

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