Electrical quadruple hysteresis in Pd-doped vanadium pentoxide nanowires due to water adsorption

由于水的吸附作用,钯掺杂五氧化二钒纳米线中出现电四重滞后现象

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Abstract

Humidity-dependent current-voltage (I-V) characteristics of Pd-doped vanadium pentoxide nanowires (Pd-VONs) were investigated. Electrical quadruple hysteresis (QH) was observed and attributed to the large amount of water molecules adsorbed on the nanowires. Using QH in Pd-VONs, the reaction of water with PdO was interpreted as the water molecules are desorbed and then dissociated with increasing bias voltage. Owing to the dissociated H(+) and OH(-) ions, PdO is reduced and oxidized. As a result, water molecules recombine as the bias voltage is decreased.

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