New enzymatically polymerized copolymers from 4-tert-butylphenol and 4-ferrocenylphenol and their modification and inclusion complexes with β-cyclodextrin

4-叔丁基苯酚与4-二茂铁基苯酚的酶促聚合新共聚物及其与β-环糊精的改性和包合物

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作者:Adam Mondrzyk, Beate Mondrzik, Sabrina Gingter, Helmut Ritter

Abstract

The enzymatically catalyzed synthesis of a copolymer of 4-tert-butylphenol and 4-ferrocenylphenol by horse radish peroxidase (HRP) in the presence of H(2)O(2) in a 1,4-dioxane/water system is described. Furthermore, polymer-analogous alkylation of the free hydroxy groups and subsequent click reaction with mono-6-azido-6-desoxy-β-cyclodextrin (N(3)-β-CD) was carried out. The formation of inter- and intramolecular inclusion complexes was investigated by DLS measurement.

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