Bis(arylimidazole) Iridium Picolinate Emitters and Preferential Dipole Orientation in Films

双(芳基咪唑)铱吡啶酸盐发射体和薄膜中的优先偶极取向

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作者:Aron J Huckaba, Alessia Senes, Sadig Aghazada, Azin Babaei, Stefan C J Meskers, Iwan Zimmermann, Pascal Schouwink, Natalia Gasilova, René A J Janssen, Henk J Bolink, Mohammad Khaja Nazeeruddin

Abstract

The straightforward synthesis and photophysical properties of a new series of heteroleptic iridium(III) bis(2-arylimidazole) picolinate complexes are reported. Each complex has been characterized by nuclear magnetic resonance, UV-vis, cyclic voltammetry, and photoluminescent angle dependency, and the emissive properties of each are described. The preferred orientation of transition dipoles in emitter/host thin films indicated more preferred orientation than homoleptic complex Ir(ppy)3.

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