High-Performance Thermochromic Multilayer Coatings of W‑Doped VO(2) Nanoparticles Dispersed in an SiO(2) Matrix Prepared on Glass at a Low Temperature

低温下在玻璃基底上制备的掺杂钨的二氧化钒纳米颗粒分散于二氧化硅基质中的高性能热致变色多层涂层

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Abstract

We report a high-performance thermochromic VO(2)-based coating prepared on standard glass at a low substrate temperature of 350 °C without opening the vacuum chamber to the atmosphere. It is formed by four layers of W-doped VO(2) nanoparticles dispersed in the SiO(2) matrix. The coating exhibits a transition temperature of 33 °C with an integral luminous transmittance of 65.4% (low-temperature state) and 60.1% (high-temperature state), and a modulation of the solar energy transmittance of 15.3%. Such a combination of properties, together with the low temperature during preparation, fulfills the requirements for large-scale implementation on building glass and has not been reported yet.

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