Ag nanoparticle-deposited TiO2 nanotube arrays for electrodes of Dye-sensitized solar cells

用于染料敏化太阳能电池电极的银纳米颗粒沉积二氧化钛纳米管阵列

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Abstract

ABSTRACT: Dye-sensitized solar cells composed of a photoanode of Ag nanoparticle (NP)-deposited TiO2 nanotube (TNT) arrays were fabricated. The TNT arrays were prepared by anodizing Ti films on fluorine-doped tin oxide (FTO)-coated glass substrates. Efficient charge transportation through the ordered nanostructure of TNT arrays should be carried out compared to conventional particulate TiO2 electrodes. However, it has been a big challenge to grow TNT arrays on FTO glass substrates with the lengths needed for sufficient light-harvesting (tens of micrometers). In this work, we deposited Ag nanoparticles (NPs) on the wall of TNT arrays to enhance light-harvesting property. Dye-sensitized solar cells with these Ag NP-deposited TNT arrays yielded a higher power conversion efficiency (2.03 %) than those without Ag NPs (1.39 %). PACS CODES: 06.60.Ei Sample preparation, 81.05.Bx Metals, Semimetals, Alloys, 81.07.De Nanotubes.

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