Enhanced Activation of Persulfate by Meso-CoFe(2)O(4)/SiO(2) with Ultrasonic Treatment for Degradation of Chlorpyrifos

超声处理增强介孔CoFe(2)O(4)/SiO(2)催化剂对过硫酸盐的活化作用,用于降解毒死蜱

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Abstract

Magnetic mesoporous CoFe(2)O(4)/SiO(2) (Meso-CoFe(2)O(4)/SiO(2)) composites were simply synthesized. On the basis of previous studies, optimum preparation conditions of their structure and physical properties can be readily determined. CoFe(2)O(4) nanocrystals and their mesoporous structure were authenticated by low-angle and wide-angle X-ray diffraction, high-resolution transmission electron microscopy, scanning electron microscopy, element mapping, X-ray photoelectron spectroscopy, nitrogen adsorption isotherms, and so on. They were applied to degrade chlorpyrifos where Meso-CoFe(2)O(4)/SiO(2) composites provide a mesoporous microenvironment and combined with ultrasonic treatment can enhance heterogeneous activation of persulfate. Research findings showed that the system can be conducive to remove quickly chlorpyrifos and the removal ratios reached 99.99%. The results provided a strategy for the chlorpyrifos degradation and, similarly, pollution control of pesticide wastewater.

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