Abstract
Organic ultrathin semiconductor nanostructures have attracted continuous attention in recent years owing to their excellent charge transport capability, favorable flexibility, solution-processability and adjustable photoelectric properties, providing opportunities for next-generation optoelectronic applications. For integrated electronics, organic ultrathin nanostructures need to be prepared as large-area patterns with precise alignment and high crystallinity to achieve organic electronic devices with high performance and high throughput. However, the fabrication of organic ultrathin nanostructure arrays still remains challenging due to uncontrollable growth along the height direction in solution processes. In this review, we first introduce the properties, assembly methods and applications of four typical organic ultrathin nanostructures, including small molecules, polymers, and other organic-inorganic hybrid materials. Five categories of representative solution-processing techniques for patterning organic micro- and nanostructures are summarized and discussed. Finally, challenges and perspectives in the controllable preparation of organic ultrathin arrays and potential applications are featured on the basis of their current development.