Preparation and Characterization of Carbon Quantum Dots (CQD) and CuFe(2)O(4)-CQD Composite Materials for Photo and Electrochemical Applications

碳量子点(CQD)和CuFe(2)O(4)-CQD复合材料的制备与表征及其在光电化学应用中的应用

阅读:1

Abstract

The Carbon quantum dots (CQD) is prepared from ascorbic acid, and the photophysical, structural, and metal sensing behavior of the CQD is investigated in detail. The negatively charged CQD, along with the vibrant functional groups, can absorb the positive charge ferric ion (Fe(3+)) and copper(II) ion or cupric ion (Cu(2+)) ions with the help of electrostatic attractive forces. In this process, the aggregation of CQD around the Fe(3+) and Cu(2+) ions results in confirmation that CQD is a fluorescence sensor probe that forms a metal complex, CQD-Fe(3+) and CQD-Cu(2+). The composite structural and functional group properties are investigated by the different analytical techniques. Moreover, the copper ferrite (CuFe(2)O(4)-CQD) electrochemical performances are evaluated in three and two-electrode systems by Cyclic voltammetry (CV), Galvanostatic charge-discharge (GCD), and Electrochemical Impedance Spectroscopy (EIS) techniques. The CuFe(2)O(4)-CQD electrode's specific capacitance value is 410 F g(-1) at 2 A g(-1) with 100% capacitance retention after 3000 cycles. Moreover, the methylene blue dye degradation efficiency of CuFe(2)O(4)-CQD is 91% in 120 min. The CuFe(2)O(4)-CQD composite has a synergistic effect between the CQD and CuFe(2)O(4), which delivers a higher photocatalytic effect because which reduced recombination and enhancing charge transport.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。