N-arylated oxathiazinane heterocycles are convenient synthons for 1,3-amino ethers and 1,3-amino thioethers
N-芳基化氧噻嗪杂环是 1,3-氨基醚和 1,3-氨基硫醚的便捷合成子
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作者：Anand H Shinde #, Someshwar Nagamalla #, Shyam Sathyamoorthi
Abstract
This communication describes a variety of nucleophilic ring openings of N-arylated oxathiazinane heterocycles. We find that this reaction is compatible with phenoxides, naphthoxides, and thiolates and allows for the rapid assembly of N-aryl-amino ethers and N-aryl-amino thioethers. Fourteen examples are shown and a mechanistic pathway is hypothesized.
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