Ambient- and elevated temperature properties of Sc- and Zr-modified Al-6Ni alloys strengthened by Al(3)Ni microfibers and Al(3)(Sc, Zr) nanoprecipitates

Sc和Zr改性Al-6Ni合金经Al(3)Ni微纤维和Al(3)(Sc,Zr)纳米析出物强化后的常温和高温性能

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Abstract

The eutectic Al-6Ni (wt.%) alloy exhibits excellent strength at ambient and elevated temperature, provided by a high volume fraction of Al(3)Ni microfibers formed during solidification. Here, Al-6Ni is micro-alloyed with Sc and Zr (with 0.1Sc+0.2Zr, 0.2Sc+0.4Zr and 0.3Sc+0.2Zr, wt.%), creating two additional populations of primary and secondary Al(3)(Sc,Zr) precipitates. The fully eutectic microstructure (α-Al + Al(3)Ni) observed in Al-6Ni alloy changes, with Sc and Zr addition to hypoeutectic microstructure with primary α-Al grains nucleated on solidification by primary Al(3)(Sc,Zr) precipitates. Upon subsequent aging, fully-coherent Al(3)(Sc,Zr) nano-precipitates form in the α-Al matrix between Al(3)Ni microfibers, providing substantial precipitation strengthening, which is maintained for up to 1 month at 350 °C. Alloy strength - both at ambient temperature and during creep at 300 °C - can be quantitatively described through a superposition of precipitation strengthening by Al(3)(Sc,Zr) nanoprecipitates and load-transfer strengthening by Al(3)Ni microfibers.

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