Abstract
In this study, we employed Principal Component Analysis (PCA) and Multi-Linear Regression (MLR) to identify the most significant sources contributing to the toxicity of PM(10) in the city center of Riyadh. PM(10) samples were collected using a medium-volume air sampler during cool (December 2019-March 2020) and warm (May 2020-August 2020) seasons, including dust and non-dust events. The collected filters were analyzed for their chemical components (i.e., water-soluble ions, metals, and trace elements) as well as oxidative potential and elemental and organic carbon (EC/OC) contents. Our measurements revealed comparable extrinsic oxidative potential (P-value = 0.30) during the warm (1.2 ± 0.1 nmol/min-m(3)) and cool (1.1 ± 0.1 nmol/min-m(3)) periods. Moreover, we observed higher extrinsic oxidative potential of PM(10) samples collected during dust events (~30% increase) compared to non-dust samples. Our PCA-MLR analysis identified soil and resuspended dust, secondary aerosol (SA), local industrial activities and petroleum refineries, and traffic emissions as the four sources contributing to the ambient PM(10) oxidative potential in central Riyadh. Soil and resuspended dust were the major source contributing to the oxidative potential of ambient PM(10), accounting for 31% of the total oxidative potential. Secondary aerosols (SA) were the next important source of PM(10) toxicity in the area as they contributed to about 20% of the PM(10) oxidative potential. Results of this study revealed the major role of soil and resuspended road dust on PM(10) toxicity and can be helpful in adopting targeted air quality policies to reduce the population exposure to PM(10).