Abstract
Sodium-ion batteries (SIBs) have been deemed to be a promising energy storage technology in terms of cost-effectiveness and sustainability. However, the electrodes often operate at potentials beyond their thermodynamic equilibrium, thus requiring the formation of interphases for kinetic stabilization. The interfaces of the anode such as typical hard carbons and sodium metals are particularly unstable because of its much lower chemical potential than the electrolyte. This creates more severe challenges for both anode and cathode interfaces when building anode-free cells to achieve higher energy densities. Manipulating the desolvation process through the nanoconfining strategy has been emphasized as an effective strategy to stabilize the interface and has attracted widespread attention. This Outlook provides a comprehensive understanding about the nanopore-based solvation structure regulation strategy and its role in building practical SIBs and anode-free batteries. Finally, guidelines for the design of better electrolytes and suggestions for constructing stable interphases are proposed from the perspective of desolvation or predesolvation.