Abstract
Electrochemical nitrogen fixation under ambient conditions is promising for sustainable ammonia production but is hampered by high reaction barrier and strong competition from hydrogen evolution, leading to low specificity and faradaic efficiency with existing catalysts. Here we describe the activation of MoS(2) in molten sodium that leads to simultaneous formation of a sulfur vacancy-rich heterostructured 1T/2H-MoS (x) monolayer via reduction and phase transformation. The resultant catalyst exhibits intrinsic activities for electrocatalytic N(2)-to-NH(3) conversion, delivering a faradaic efficiency of 20.5% and an average NH(3) rate of 93.2 μg h(-1) mg(cat) (-1). The interfacial heterojunctions with sulfur vacancies function synergistically to increase electron localization for locking up nitrogen and suppressing proton recombination. The 1T phase facilitates H-OH dissociation, with S serving as H-shuttling sites and to stabilize . The subsequently couple with nearby N(2) and NH (x) intermediates bound at Mo sites, thus greatly promoting the activity of the catalyst. First-principles calculations revealed that the heterojunction with sulfur vacancies effectively lowered the energy barrier in the potential-determining step for nitrogen reduction, and, in combination with operando spectroscopic analysis, validated the associative electrochemical nitrogen reduction pathway. This work provides new insights on manipulating chalcogenide vacancies and phase junctions for preparing monolayered MoS(2) with unique catalytic properties.