Abstract
There is an increasing need to find cost-effective and sustainable solutions for treating wastewater from contaminants of emerging concern (CECs). In this regard, cape gooseberry husk-typically an agri-food waste-is investigated for the first time as a potential biosorbent for the removal of model pharmaceutical contaminants of caffeine (CA) and salicylic acid (SA) from water. Three different preparations of husks were investigated and characterized using Fourier transform infrared spectroscopy, scanning electron microscopy, Brunauer-Emmett-Teller analysis, zeta potential, and point of zero charge measurements. The activation of the husk led to an increase in the surface area, pore volume, average pore size, and adsorption favorability. The single-component adsorption of SA and CA onto the three husks was investigated at different initial concentrations and pH values to determine the optimal operating conditions. The maximal removal efficiencies of SA and CA reached up to 85 and 63%, respectively, for the optimal husk which also offers a less energy-intensive option in its activation. This husk also exhibited high rates of adsorption that exceeded other husk preparations by up to four times. It was proposed that CA interacts electrostatically with the husk, while SA binds through weak physical interactions (e.g., van der Waals and H-bonding). In binary systems, CA adsorption was highly favored over SA adsorption, owing to its electrostatic interactions. The selectivity coefficients αSACA varied with initial concentration and ranged between 61 and 627. The regeneration of husk was also successful resulting in its re-use for up to four full consecutive cycles, further demonstrating the efficiency of cape gooseberry husk use in wastewater treatment.