Effect of Rare-Earth Co-Doping on the Trap Level Concentrations in Silica Glasses: Experimental and Theoretical Study of the Light Emission Under X-Rays for Dosimetry Applications

稀土共掺杂对二氧化硅玻璃中陷阱能级浓度的影响:X射线照射下发光的实验和理论研究及其在剂量测定中的应用

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Abstract

In this paper, an experimental and theoretical study was undertaken to assess the impact of rare-earth co-doping of silica glasses on the light emission under X-rays. To this aim, radioluminescence (RL), phosphorescence (PP), and thermoluminescence (TL) signals of Ce(3+)/Gd(3+) co-doped silica glasses have been successively measured and combined at different dose rates and irradiation temperatures. The RL response of the weakly co-doped sample was found to be temperature-independent between 273 K and 353 K. This result suggests that, based on this RL response, it is possible to design ionizing radiation sensors independent of the irradiation temperature in the corresponding range. Moreover, a model that considers the electron-hole pair generation, the charge carrier trapping-detrapping, and the electron-hole recombination in the localized and delocalized bands has been developed to reproduce these optical signals. The theoretical model also explains the temperature independence of the RL response between 273 K and 353 K for the weakly co-doped sample and, therefore, the operating principle of an X-ray sensor independent of the irradiation temperature.

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