Assessment of Time-Dependent Hydration Products in Olivine-Substituted Cement Mortars

橄榄石替代水泥砂浆中随时间变化的水化产物的评估

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Abstract

It is known that approximately 8% of atmospheric carbon dioxide (CO(2)) emissions originate from cement production. Consequently, there is ongoing rapid research into environmentally friendly and alternative materials that could substitute for cement. Olivine [(Mg, Fe)(2)SiO(4)] is an abundant mineral in the Earth's crust that facilitates CO(2) sequestration due to its high solubility. This study investigates the effects of hydration mechanisms in olivine-substituted cement mortars on their compressive strength, microstructural characteristics, and physical properties. For this purpose, standard cement mortars were produced using CEM IV 32.5 N-type cement with olivine substitution rates of 0%, 10%, and 20%. The compressive strength of the specimens was initially determined at 7, 28, and 90 days. Subsequently, the hydration mechanisms at 7, 28, and 90 days were characterized using X-ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Differential Thermal Analysis/Thermogravimetric Analysis (DTA/TG), and Scanning Electron Microscopy-Energy Dispersive Spectroscopy (SEM-EDS). The results demonstrated that the 10% substitution rate complies with the BS EN 196-1 standard, and olivine can be substituted for CEM IV type cement up to 10% without requiring calcination.

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