Continuous flame aerosol synthesis of carbon-coated nano-LiFePO(4) for Li-ion batteries

用于锂离子电池的碳包覆纳米LiFePO(4)的连续火焰气溶胶合成

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Abstract

Core-shell, nano-sized LiFePO(4)-carbon particles were made in one step by scalable flame aerosol technology at 7 g/h. Core LiFePO(4) particles were made in an enclosed flame spray pyrolysis (FSP) unit and were coated in-situ downstream by auto thermal carbonization (pyrolysis) of swirl-fed C(2)H(2) in an O(2)-controlled atmosphere. The formation of acetylene carbon black (ACB) shell was investigated as a function of the process fuel-oxidant equivalence ratio (EQR). The core-shell morphology was obtained at slightly fuel-rich conditions (1.0

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