A new pH sensitive fluorescent and white light emissive material through controlled intermolecular charge transfer

一种通过可控分子间电荷转移实现的新型pH敏感荧光和白光发射材料

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Abstract

A new, pH dependent and water-soluble, conjugated oligomer (amino, trimethylammonium oligophenylene vinylene, ATAOPV) was synthesized with a quaternary ammonium salt and an aromatic amine at the two ends of a π-conjugated oligomer, thus creating a strong dipole across the molecule. A unique white light LED is successfully fabricated from a stimuli responsive organic molecule whose emission properties are dominated by the pH value of the solution through controlled intermolecular charge transfer.

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