Powder Synthesis and Characterization of Al(0.5)CoCrFeNi High-Entropy Alloy for Additive Manufacturing Prepared by the Plasma Rotating Electrode Process

采用等离子旋转电极法制备用于增材制造的Al(0.5)CoCrFeNi高熵合金粉末,并对其进行表征

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Abstract

The Al(0.5)CoCrFeNi high-entropy alloy powder was produced by using a plasma rotating electrode process. The morphology, microstructure, and physical properties of the powder were characterized. The powder exhibited a smooth surface and a narrow particle size distribution with a single peak. The relationships between particle size and secondary dendrite arm space as well as cooling rate were evaluated as follows: λ = 0.0105d + 0.062 and v(c) = 4.34 × 10(-5)d(-2) + 2.62 × 10(-2)d(-3/2), respectively. The Al(0.5)CoCrFeNi powder mainly consisted of fcc + bcc phases. As the powder particle size decreased, the microstructure of the powder changed from dendritic to columnar or equiaxed, along with a decrease in the fcc content and an increase in the bcc content. The tap density (4.76 g cm(-3)), flowability (15.01 s × 50 g(-1)), oxygen content (<300 ppm), and sphericity (>94%) of the powder indicated suitability for additive manufacturing.

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