On spin-exchange and electron-transfer rates in bacterial photosynthesis

细菌光合作用中的自旋交换和电子转移速率

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Abstract

A discrepancy is explored regarding the spin exchange integral estimated from magnetic field effects on recombination of the bacteriochlorophyll dimer cation (Bchl)(2)+ and the bacteriopheophytin anion Bph(-) and the measured electron transfer rate between Bph and electronically excited (Bchl)(2). In one explanation considered here there are two sites for the electron or for the hole, with a hopping between sites.

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