Growth of graphene with large single-crystal domains by Ni foam-assisted structure and its high-gain field-effect transistors

利用镍泡沫辅助结构生长具有大单晶畴的石墨烯及其高增益场效应晶体管

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Abstract

High-quality graphene materials and high-performance graphene transistors have attracted much attention in recent years. To obtain high-performance graphene transistors, large single-crystal graphene is needed. The synthesis of large-domain-sized single-crystal graphene requires low nucleation density; this can lead to a lower growth rate. In this study, a Ni-foam assisted structure was developed to control the nucleation density and growth rate of graphene by tuning the flow dynamics. Lower nucleation density and high growth rate (∼50 μm min(-1)) were achieved with a 4 mm-gap Ni foam. With the graphene transistor fabrication process, a pre-deposited Au film as the protective layer was used during the graphene transfer. Graphene transistors showed good current saturation with drain differential conductance as low as 0.04 S mm(-1) in the strong saturation region. For the devices with gate length of 2 μm, the intrinsic cut-off frequency f (T) and maximum oscillation frequency f (max) were 8.4 and 16.3 GHz, respectively, with f (max)/f (T) = 1.9 and power gain of up to 6.4 dB at 1 GHz. The electron velocity saturation induced by the surface optical phonons of SiO(2) substrates was analyzed. Electron velocity saturation and ultra-thin Al(2)O(3) gate dielectrics were thought to be the reasons for the good current saturation and high power gain of the graphene transistors.

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