Abstract
Since titanium alloys have been widely used as joint replacement biomaterials, their superficial lubrication has evolved to be a critical factor for normal use. For this purpose, one kind of typical microgel, poly(NIPAAm-co-AA), was synthesized by emulsifier-free emulsion polymerization and used as an aqueous lubricating additive between titanium alloy contacts. The results show that the as-synthesized microgels reduced the coefficient of friction by 46% and the wear volume by 45%, compared with pure water. Meanwhile, due to their thermosensitive property, the microgels were employed as smart additives to modulate the interfacial friction, which was attributed to the transition of the hydrated state and the elastic deformation of microgel particles. To further dissect the lubrication mechanism, it was found that the lubricating property of microgels was substantially associated with the formation of a hydrated layer surrounding microgels, microbearing effect, interfacial adsorption, and the colloidal stability. Looking beyond, as one kind of soft colloidal lubricant, the microgels may play an important role in the biomedical metal lubrication.