Design of Wood-Based Gd (III)-Hemoporphyrin Monomethyl Ether Eco-Material for Optical Oxygen Sensing with a Wide Detection Range

设计一种基于木质的Gd(III)-血卟啉单甲醚环保材料,用于具有宽检测范围的光学氧传感

阅读:1

Abstract

Gaseous oxygen detection is essential in numerous production and manufacturing sectors. To meet the varying oxygen detection requirements across different fields, techniques that offer a wide oxygen detection range should be developed. In this study, a wood-based oxygen sensing material was designed using balsa wood as the supporting matrix and gadolinium hemoporphyrin monomethyl ether (Gd-HMME) as the oxygen-sensitive indicator. The wood-based Gd-HMME exhibits a cellular porous structure, which not only facilitates the loading of a substantial number of indicator molecules but also enables the rapid interaction between indicators and oxygen molecules. OP is defined as the ratio of the phosphorescence intensity of the oxygen-sensing material in the anaerobic and aerobic environment. A linear relationship between OP and oxygen partial pressure ([O(2)]) was obtained within the whole range of [O(2)] (0-100 kPa). The wood-based Gd-HMME exhibited excellent resistance to photobleaching, along with a rapid response time (3.9 s) and recovery time (4.4 s). It was demonstrated that the measurement results obtained using wood-based Gd-HMME were not influenced by other gaseous components present in the air. An automatic oxygen detection system was developed using LabVIEW for practical use, and the limit of detection was determined to be 0.01 kPa.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。