Multifunctional Dy2NiMnO6/Reduced Graphene Oxide Nanocomposites and Their Catalytic, Electromagnetic Shielding, and Electrochemical Properties

多功能 Dy2NiMnO6/还原氧化石墨烯纳米复合材料及其催化、电磁屏蔽和电化学性能

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作者:Bibhuti Bhusan Sahoo, Prasanta Kumar Sahoo, Vijayabhaskara Rao Bhaviripudi, Krushna Chandra Sahu, Abhishek Tripathi, Naresh Kumar Sahoo, Radhamanohar Aepuru, Vishwajit M Gaikwad, Srikant Sahoo, Ashis Kumar Satpati, Chuan-Pei Lee0

Abstract

Multifunctional nanocomposites have shown great interest in clean energy systems and environmental applications in recent years. Herein, we first reported the synthesis of Dy2NiMnO6 (DNMO)/reduced graphene oxide (rGO) nanocomposites utilizing a hybrid approach involving sol-gel and solvothermal processes. Subsequently, we investigated these nanocomposites for their applications in catalysis, electromagnetic interference shielding, and supercapacitors. A morphological study suggests spherical-shaped DNMO nanoparticles of an average size of 382 nm that are uniformly distributed throughout the surface without any agglomeration. The as-prepared nanocomposites were used as catalysts to investigate the catalytic reduction of 4-nitrophenol in the presence of NaBH4. DNMO/rGO nanocomposites demonstrate superior catalytic activity when compared with bare DNMO, with the rate of reduction being influenced by the composition of the DNMO/rGO nanocomposites. In addition, novel multifunctional DNMO/rGO was incorporated into polyvinylidene difluoride (PVDF) to develop a flexible nanocomposite for electromagnetic shielding applications and exhibited a shielding effectiveness of 6 dB with 75% attenuation at a frequency of 8.5 GHz compared to bare PVDF and PVDF-DNMO nanocomposite. Furthermore, the electrochemical performance of DNMO/rGO nanocomposites was investigated as an electrode material for supercapacitors, exhibiting the highest specific capacitance of 260 F/g at 1 A/g. These findings provide valuable insights into the design of DNMO/rGO nanocomposites with remarkable performance in sustainable energy and environmental applications.

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