Thermal conductivity of carbon nanotubes and graphene in epoxy nanofluids and nanocomposites

环氧纳米流体和纳米复合材料中碳纳米管和石墨烯的热导率

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作者:Mario Martin-Gallego, Raquel Verdejo, Mohamed Khayet, Jose Maria Ortiz de Zarate, Mohamed Essalhi, Miguel Angel Lopez-Manchado

Abstract

We employed an easy and direct method to measure the thermal conductivity of epoxy in the liquid (nanofluid) and solid (nanocomposite) states using both rodlike and platelet-like carbon-based nanostructures. Comparing the experimental results with the theoretical model, an anomalous enhancement was obtained with multiwall carbon nanotubes, probably due to their layered structure and lowest surface resistance. Puzzling results for functionalized graphene sheet nanocomposites suggest that phonon coupling of the vibrational modes of the graphene and of the polymeric matrix plays a dominant role on the thermal conductivities of the liquid and solid states.PACS: 74.25.fc; 81.05.Qk; 81.07.Pr.

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