Doping concentration dependence of microstructure and magnetic behaviours in Co-doped TiO2 nanorods

共掺杂 TiO2 纳米棒微结构和磁行为的掺杂浓度依赖性

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作者:Li-Ting Tseng, Xi Luo, Thiam Teck Tan, Sean Li, Jiabao Yi

Abstract

Co-doped titanium dioxide (TiO2) nanorods with different doping concentrations were fabricated by a molten salt method. It is found that the morphology of TiO2 changes from nanorods to nanoparticles with increasing doping concentration. The mechanism for the structure and phase evolution is investigated in detail. Undoped TiO2 nanorods show strong ferromagnetism at room temperature, whereas incorporating of Co deteriorates the ferromagnetic ordering. X-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR) results demonstrate that the ferromagnetism is associated with Ti vacancy.

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