Abstract
This study investigates the effects of chromium (0.4~1.2) Cr content and temperature (35-80 °C) on the corrosion behavior and mechanisms of steels in a water-saturated supercritical CO(2) (S-CO(2)) environment, aiming to provide theoretical foundations for material selection and corrosion management in S-CO(2) pipeline systems. Results indicate that increasing Cr content promotes the formation of granular bainite as the dominant microstructure, accompanied by refined martensite-austenite (MA) constituents with increased population and reduced dimensions, leading to enhanced strength at the expense of toughness. In the S-CO(2)/H(2)O environment, Cr reacts with CO(2) to form a dense Cr(2)O(3) layer, significantly suppressing the corrosion rate. Temperature critically governs corrosion kinetics: at 35 °C, where S-CO(2) exhibits maximum density and CO(2) solubility in water peaks, electrochemical corrosion dominates, resulting in the highest corrosion rate. As temperature rises, the corrosion mechanism transitions to chemical corrosion, while accelerated formation of protective corrosion product films further reduces corrosion rates. Mechanistic analysis reveals that uniform corrosion arises from carbonic acid generated by water dissolution in S-CO(2), whereas localized corrosion intensifies upon direct contact between precipitated aqueous phases and the steel surface. These findings offer critical theoretical foundations for optimizing material design, operational parameters, and corrosion mitigation strategies in S-CO(2) transportation infrastructure.