An Fe(II)-catalyzed synthesis of spiro[indoline-3,2'-pyrrolidine] derivatives

Fe(II)催化的螺[吲哚啉-3,2'-吡咯烷]衍生物的合成

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Abstract

A synthetic strategy for the preparation of spiro[indoline-3,2'-pyrrolidine] derivatives has been developed, featuring a two-step sequence consisting of the reaction of 2-arylindoles with α,β-unsaturated ketones, followed by Fe(II)-catalyzed spirocyclization of readily accessible oxime acetates. The method exhibits a broad substrate scope and good functional group tolerance. The synthesized spirocyclic compounds showed no significant antimicrobial activity.

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