Industrial Potential of Formaldehyde Gas Sensor Based on PdPt Bimetallic Loaded SnO(2) Nanoparticles

基于PdPt双金属负载SnO(2)纳米粒子的甲醛气体传感器的工业应用潜力

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Abstract

SnO(2)-based semiconductor gas-sensing materials are regarded as some of the most crucial sensing materials, owing to their extremely high electron mobility, high sensitivity, and excellent stability. To bridge the gap between laboratory-scale SnO(2) and its industrial applications, low-cost and high-efficiency requirements must be met. This implies the need for simple synthesis techniques, reduced energy consumption, and satisfactory gas-sensing performances. In this study, we utilized a surfactant-free simple method to modify SnO(2) nanoparticles with PdPt noble metals, ensuring the stable state of the material. Under the synergistic catalytic effect of Pd and Pt, the composite material (1.0 wt%-PdPt-SnO(2)) significantly enhanced its response to HCHO. This modification decreased the optimal working temperature to as low as 180 °C to achieve a response value (R(a)/R(g) = 8.2) and showcased lower operating temperatures, higher sensitivity, and better selectivity to detect 10 ppm of HCHO when compared with pristine SnO(2) or single noble metal-decorated SnO(2) sensors. Stability tests verified that the gas sensor signals based on PdPt-SnO(2) nanoparticles exhibit good reliability. Furthermore, a portable HCHO detector was designed for practical applications, such as in newly purchased cushions, indicating its potential for industrialization beyond the laboratory.

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