A Pd-containing ionic liquid modified magnetic graphene oxide nanocomposite (Fe(3)O(4)/GO-IL-Pd) as a powerful catalyst for the reduction of nitrobenzenes

一种含钯离子液体改性的磁性氧化石墨烯纳米复合材料(Fe(3)O(4)/GO-IL-Pd)作为硝基苯还原的强催化剂

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Abstract

A novel palladium-containing ionic liquid-modified magnetic graphene oxide nanocomposite (Fe(3)O(4)/GO-IL-Pd) is synthesized and its catalytic performance is studied in the reduction of nitrobenzenes. The Fe(3)O(4)/GO-IL-Pd nanocomposite was characterized by using FT-IR, PXRD, SEM, EDS, VSM, and TG analyses. These analyses showed good magnetic properties and high stability of the designed composite. Different derivatives of nitrobenzenes were applied as substrates, giving corresponding anilines in high to excellent yields (89-96%) at short reaction times (10-15 minutes). Also, the stability, reproducibility, and reusability of the Fe(3)O(4)/GO-IL-Pd nanocomposite were investigated under applied conditions. A leaching experiment was also performed to study the nature of the Fe(3)O(4)/GO-IL-Pd catalyst under the conditions used.

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