Electrochemical Detection of Ammonia in Water Using NiCu Carbonate Hydroxide-Modified Carbon Cloth Electrodes: A Simple Sensing Method

利用镍铜碳酸盐氢氧化物修饰碳布电极电化学检测水中氨:一种简便的传感方法

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Abstract

Excessive ammonia nitrogen can potentially compromise the safety of drinking water. Therefore, developing a rapid and simple detection method for ammonia nitrogen in drinking water is of great importance. Nickel-copper hydroxides exhibit strong catalytic capabilities and are widely applied in ammonia nitrogen oxidation. In this study, a self-supported electrode made of nickel-copper carbonate hydroxide was synthesized on a carbon cloth collector via a straightforward one-step hydrothermal method for rapid ammonia nitrogen detection in water. It exhibits sensitivities of 3.9 μA μM(-1) cm(-2) and 3.13 μA μM(-1) cm(-2) within linear ranges of 1 μM to 100 μM and 100 μM to 400 μM, respectively, using a simple and rapid i-t method. The detection limit is as low as 0.62 μM, highlighting its excellent anti-interference properties against various anions and cations. The methodology's simplicity and effectiveness suggest broad applicability in water quality monitoring and environmental protection, particularly due to its significant cost-effectiveness.

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