Palladium nanoparticles immobilized in SnFe(2)O(4)/SiO(2)/PM as efficient heterogeneous catalysts for the suzuki cross-coupling reaction

负载于SnFe(2)O(4)/SiO(2)/PM中的钯纳米粒子作为高效的非均相催化剂用于铃木交叉偶联反应

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Abstract

This study focuses on the synthesis of a novel magnetic interphase palladium catalyst immobilized on pyromellitic dianhydride (PM)-coated magnetic SnFe(2)O(4) nanoparticles. Such surface functionalization of magnetic particles represents a promising strategy to bridge the gap between heterogeneous and homogeneous catalysis methods. The structure, morphology, and physicochemical properties of these particles were thoroughly examined using various analytical techniques, including FT-IR, SEM, XRD, VSM, ICP, and EDS. The resulting SnFe(2)O(4)/SiO(2)/PM-Pd nanocatalyst exhibited excellent catalytic performance as a recyclable catalyst in Suzuki-Miyaura cross-coupling reactions at room temperature. Additionally, the catalyst demonstrated high reusability, showing minimal palladium leaching and no significant loss in activity across multiple cycles.

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