Ag(+) doped into azo-linked conjugated microporous polymer for volatile iodine capture and detection of heavy metal ions

将Ag(+)掺杂到偶氮键合的共轭微孔聚合物中,用于挥发性碘的捕获和重金属离子的检测

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Abstract

We herein report the construction of a novel azo-linked conjugated microporous polymers (Ag@Azo(TPE)-CMP), which possesses permanent porous structure and Ag(+) loading up of 7.62% in the skeleton as effective sorption sites. Ag@Azo(TPE)-CMP shows considerable adsorption capacity of iodine of 202 wt% in iodine vapor at 350 K. In addition, Ag@Azo(TPE)-CMP can effectively remove heavy ions from ethanol-water solution.

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