Abstract
Determination of food freshness, which is the most ancient role of the human sense of smell, is still a challenge for compact and inexpensive electronic nose devices. Fast, sensitive, and reusable sensors are long-awaited in the food industry to replace slow, labor-intensive, and expensive bacteriological methods. In this work, we present microbiological verification of a novel approach to food quality monitoring and spoilage detection using an electronic nose based on organic field-effect transistors (OFETs) and its application for distinguishing products. The compact device presented is able to detect spoilage-related gases as early as at the 4 × 10(4) CFU g(-1) bacteria count level, which is 2 orders of magnitude below the safe consumption threshold. Cross-selective sensor array based on OFETs with metalloporphyrin receptors were made on a single substrate using solution processing leading to a low production cost. Moreover, machine learning methods applied to the sensor array response allowed us to compare spoilage profiles and separate them by the type of food: pork, chicken, fish, or milk. The approach presented can be used to monitor food spoilage and distinguish different products with an affordable and portable device.