Abstract
Herein, the promotional effects of Mg, Fe, and Pt on Ni-based catalysts supported on Al2O3-CeO2 (Ni/Al2O3-CeO2) were investigated in the dry reforming of methane (DRM) reaction. The interaction of a suitable amount of MgO and FeO with Ce2O3 stabilized in the catalysts was demonstrated by the temperature-programmed desorption of CO2 (CO2-TPD). Ce2O3 has a high basicity for adsorbing CO2, generating a monoclinic Ce2O2CO3 species in the DRM reaction. Surface oxygen ions were also produced by adding MgO and FeO, as demonstrated by the temperature-programmed reduction of H2 (H2-TPR). Monoclinic Ce2O2CO3 and surface oxygen may both be used to oxidize and remove the carbon that was deposited, maintaining the high activity and stability of the metal Ni and Pt catalysts. The high dispersion and synergistic interactions between the platinum and oxide phases, which are associated with the decrease in reduction temperature and the rise in the number of basic sites, are responsible for the increased activity of Pt with M-Ni/Al2O3-CeO2 catalysts. The co-doped Ni/Al2O3-CeO2 catalysts with Mg and Fe significantly enhanced the activity (more than 80% methane and 84% CO2 conversion), the selectivity toward syngas (∼90%), and maintained the H2/CO ratio at about 0.97 at 700 °C.