Abstract
In this paper, a highly sensitive methane (CH(4)) sensor based on light-induced thermoelastic spectroscopy (LITES) and a T-shaped quartz tuning fork (QTF) with hydrogen (H(2)) and helium (He) enhancement techniques are reported for the first time. The low resonant frequency self-designed T-shaped QTF was exploited for improving the energy accumulation time. H(2) and He were utilized as surrounding gases for the T-shaped QTF to minimize energy loss, thereby enhancing the sensitivity of the LITES sensor. Additionally, a fiber-coupled multi-pass cell (FC-MPC) with a 40 m optical length was utilized to improve the optical absorption of CH(4). The frequency response of the T-shaped QTF with different concentrations of H(2) and He was investigated, and the Q factor in the H(2) and He environment increased significantly. Compared to operating QTF in a nitrogen (N(2)) environment, the signal amplitude was enhanced by 2.9 times and 1.9 times in pure H(2) and He environments, respectively. This enhancement corresponded to a minimum detection limit (MDL) of 80.3 ppb and 113.6 ppb. Under different CH(4) concentrations, the T-shaped QTF-based H(2)-enhanced CH(4)-LITES sensor showed an excellent linear response. Furthermore, through Allan deviation analysis, the MDL of the T-shaped QTF-based H(2)-enhanced CH(4)-LITES can reach 38 ppb with an 800 s integration time.