Hexadecylpyridinium bromides as a new capping agent for improving stability and luminescence of cesium lead bromide perovskites

十六烷基吡啶溴化物作为一种新型封端剂,可提高铯铅溴钙钛矿的稳定性和发光性能

阅读:1

Abstract

Because of exception properties, inorganic halide perovskites are promising materials for numerous applications. The efficiency of these materials are evaluated based on their photoluminescence quantum yield, which is the key indicator and proportional to the stability of the perovskite. Hence, to limit the instability of the perovskites, addition of surfactant as ligand has been applied during synthesis of nanoparticle based inorganic perovskite CsPbBr(3). As far as we know, only a few researchers have studied the impact of hexadecylpyridinium bromide (CPB) on the stability of the crystal structure of CsPbBr(3). In this work, we present a novel approach for lead halide perovskites by incorporating CPB to primarily maintain the perovskite's crystal structure, and later on to enhance the stability of CsPbBr(3) NPs while boosting its photoluminescence quantum yield (PLQY). Results showed that CPB enhanced the thermal stability and boosted the PLQY to 90 %. Moreover, CPB had proven its efficiency as a capping agent preventing the exchange of anion between bromide and iodide ions in presence of lead iodide.

特别声明

1、本页面内容包含部分的内容是基于公开信息的合理引用;引用内容仅为补充信息,不代表本站立场。

2、若认为本页面引用内容涉及侵权,请及时与本站联系,我们将第一时间处理。

3、其他媒体/个人如需使用本页面原创内容,需注明“来源:[生知库]”并获得授权;使用引用内容的,需自行联系原作者获得许可。

4、投稿及合作请联系:info@biocloudy.com。